A Simple Graph-Theoretic Construct Outlines Much of the Physics of the Multichannel Kondo Effect!

May  5, 2023

In this work, we elucidate the importance of ground-state degeneracy and frustration in determining the physics of the multichannel Kondo model.

J. Phys.: Condens. Matter 35 315601 (2023)

The physics of frustration

Frustration. We think we understand it, and how to deal with it. But what does frustration refer to in a quantum system? Consider classical spins (i.e., spins that have only two configurations, say, pointing up and pointing down) placed on a triangle and interacting with one another through a nearest neighbour antiferromagnetic Ising exchange interaction. It is easy to see that Néel (anti-parallel) ordering is no longer possible: for any two spins that are anti-aligned with one another, the third is left confused on which direction to choose. This confusion is labelled as the frustration of the classical Néel order.

An example of classical frustration: three spins on a triangle, connected by antiferromagnetic Ising interaction that favours antiparallel alignment. If the blue and green spins align in opposite directions, the third gray spin experiences conflicting interactions from the blue and green spins that want to align it downwards & upwards respectively.

Frustration can also been seen in quantum mechanical systems: while two quantum spin 1/2s with an antiferromagnetic Heisenberg interaction will form a maximally-entangled singlet state, introducing a third spin-1/2 creates a dilemma - the two-spin singlet cannot accommodate another spin (often curiously referred to as entanglement monogamy). Since the spin-flip quantum fluctuations of the system will want to lower the energy of the system by entangling all three spins, no spin can be left free and the two-spin singlet cannot be the true ground-state.

An example of quantum frustration: three spins on a triangle connected by antiferromagnetic Heisenbeg interaction. The spin-flip fluctuations favour a singlet ground-state. However, if the blue and green spins form a maximally-entangled singlet state, they can no longer bind with the third gray spin (a property of the singlet), even though there are unquenched Heisenberg interactions between the third spin and the other spins respectively.

Frustration in the multichannel Kondo problem

The multichannel Kondo problem involves a local antiferromagnetic Heisenberg interaction between a single spin-1/2 impurity and the electrons of several conduction bath channels. Had there been only one conduction bath, the impurity moment would form a singlet together with a “cloud” of electrons from the bath. We refer to this as the screening of the impurity moment (as the singlet has no magnetisation). However, in the multichannel Kondo problem described above, the formation of a singlet between the impurity and electron from one of the conduction channels is frustrated. As a result, the so-called Kondo screening of the impurity spin’s magnetic moment is hampered.

Schematic of a multichannel Kondo model. The central impurity spin interacts with two conduction bath channels (brown and blue) through spin-flip interactions. The two channels compete with each other in trying to form a singlet with the single impurity spin, resulting in a novel frustrated ground-state.

Indeed, if the total spin of the conduction bath is greater than the spin of the impurity, the multichannel Kondo problem is said to be over-screened. The screening process, as well as its breakdown, are truly many-body in nature: a macroscopic number of conduction electrons interact with a single quantum impurity, and are therefore “aware” of each other. A proper description of the physics thus requires a field-theoretic treatment of the impurity-bath interactions, and the problem has been studied using a wide variety of powerful analytic and numerical methods.

Emergence of a “stargraph” in the multichannel Kondo problem

Our contribution in this work was to show that the fascinating properties of the N-channel Kondo problem could be linked to those of the associated skeletal problem: a central quantum spin-1/2 coupled to N quantum spin-1/2s (corresponding to the N conduction channels) through identical antiferromagnetic Heisenberg exchange couplings. Such a model is often referred to as a star graph, and it can be identified as a limit of the multichannel problem in which the kinetic energy of the itinerant electrons has been switched off.

A schematic of the stargraph model, the skeletal problem associated with any multichannel Kondo model. The graph consists of a central node (the impurity spin) connected with a number of outer nodes (the local spins of the conduction channels). The bonds connecting the nodes depict the Heisenberg interaction between the impurity spin and the conduction bath spins.

We show in our work that certain properties of the star graph, such as the ground-state degeneracy and the magnetisation, are linked to bulk thermodynamic properties. The star graph also sets the scattering phase shift of the conduction electrons, and the scattering phase shift then dictates how the quantum fluctuations resolve themselves in order to lead to novel features. In this way, the quantum frustration inherent in the underlying simple quantum mechanical problem is seen to offer great insights into a many-body problem which looks quite daunting otherwise. Please read our work to find out more.

Further details on our results (mostly for the experts)